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Suzanne Y Oreilly - One of the best experts on this subject based on the ideXlab platform.
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zircon Crystal Morphology trace element signatures and hf isotope composition as a tool for petrogenetic modelling examples from eastern australian granitoids
Journal of Petrology, 2006Co-Authors: E A Belousova, W L Griffin, Suzanne Y OreillyAbstract:In situ laser ablation inductively coupled plasma mass spectrometry analysis of trace elements, U–Pb ages and Hf isotopic compositions of magmatic zircon from I- and S-type granitoids from the Lachlan Fold Belt (Berridale adamellite and Kosciusko tonalite) and New England Fold Belt (Dundee rhyodacite ignimbrite), Eastern Australia, is combined with detailed studies of Crystal Morphology to model petrogenetic processes. The presented examples demonstrate that changes in zircon Morphology, within single grains and between populations, generally correlate with changes in trace element and Hf-isotope signatures, reflecting the mixing of magmas and changes in the composition of the magma through mingling processes and progressive Crystallization. The zircon data show that the I-type Kosciusko tonalite was derived from a single source of crustal origin, whereas the S-type Berridale adamellite had two distinct sources including a significant I-type magma contribution. Complex Morphology and Hf isotope variations in zircon grains indicate a moderate contribution from a crustal component in the genesis of the I-type Dundee rhyodacite. The integration of data on Morphology, trace elements and Hf isotope variations in zircon populations provides a tool for the detailed analysis of the evolution of individual igneous rocks; it offers new insights into the contributions of different source rocks and the importance of magma mixing in granite petrogenesis. Such information is rarely obtainable from the analysis of bulk rocks.
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zircon Crystal Morphology trace element signatures and hf isotope composition as a tool for petrogenetic modelling examples from eastern australian granitoids
Journal of Petrology, 2006Co-Authors: E A Belousova, W L Griffin, Suzanne Y OreillyAbstract:In situ laser ablation inductively coupled plasma mass spectrometry analysis of trace elements, U–Pb ages and Hf isotopic compositions of magmatic zircon from I- and S-type granitoids from the Lachlan Fold Belt (Berridale adamellite and Kosciusko tonalite) and New England Fold Belt (Dundee rhyodacite ignimbrite), Eastern Australia, is combined with detailed studies of Crystal Morphology to model petrogenetic processes. The presented examples demonstrate that changes in zircon Morphology, within single grains and between populations, generally correlate with changes in trace element and Hf-isotope signatures, reflecting the mixing of magmas and changes in the composition of the magma through mingling processes and progressive Crystallization. The zircon data show that the I-type Kosciusko tonalite was derived from a single source of crustal origin, whereas the S-type Berridale adamellite had two distinct sources including a significant I-type magma contribution. Complex Morphology and Hf isotope variations in zircon grains indicate a moderate contribution from a crustal component in the genesis of the I-type Dundee rhyodacite. The integration of data on Morphology, trace elements and Hf isotope variations in zircon populations provides a tool for the detailed analysis of the evolution of individual igneous rocks; it offers new insights into the contributions of different source rocks and the importance of magma mixing in granite petrogenesis. Such information is rarely obtainable from the analysis of bulk rocks.
E A Belousova - One of the best experts on this subject based on the ideXlab platform.
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zircon Crystal Morphology trace element signatures and hf isotope composition as a tool for petrogenetic modelling examples from eastern australian granitoids
Journal of Petrology, 2006Co-Authors: E A Belousova, W L Griffin, Suzanne Y OreillyAbstract:In situ laser ablation inductively coupled plasma mass spectrometry analysis of trace elements, U–Pb ages and Hf isotopic compositions of magmatic zircon from I- and S-type granitoids from the Lachlan Fold Belt (Berridale adamellite and Kosciusko tonalite) and New England Fold Belt (Dundee rhyodacite ignimbrite), Eastern Australia, is combined with detailed studies of Crystal Morphology to model petrogenetic processes. The presented examples demonstrate that changes in zircon Morphology, within single grains and between populations, generally correlate with changes in trace element and Hf-isotope signatures, reflecting the mixing of magmas and changes in the composition of the magma through mingling processes and progressive Crystallization. The zircon data show that the I-type Kosciusko tonalite was derived from a single source of crustal origin, whereas the S-type Berridale adamellite had two distinct sources including a significant I-type magma contribution. Complex Morphology and Hf isotope variations in zircon grains indicate a moderate contribution from a crustal component in the genesis of the I-type Dundee rhyodacite. The integration of data on Morphology, trace elements and Hf isotope variations in zircon populations provides a tool for the detailed analysis of the evolution of individual igneous rocks; it offers new insights into the contributions of different source rocks and the importance of magma mixing in granite petrogenesis. Such information is rarely obtainable from the analysis of bulk rocks.
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zircon Crystal Morphology trace element signatures and hf isotope composition as a tool for petrogenetic modelling examples from eastern australian granitoids
Journal of Petrology, 2006Co-Authors: E A Belousova, W L Griffin, Suzanne Y OreillyAbstract:In situ laser ablation inductively coupled plasma mass spectrometry analysis of trace elements, U–Pb ages and Hf isotopic compositions of magmatic zircon from I- and S-type granitoids from the Lachlan Fold Belt (Berridale adamellite and Kosciusko tonalite) and New England Fold Belt (Dundee rhyodacite ignimbrite), Eastern Australia, is combined with detailed studies of Crystal Morphology to model petrogenetic processes. The presented examples demonstrate that changes in zircon Morphology, within single grains and between populations, generally correlate with changes in trace element and Hf-isotope signatures, reflecting the mixing of magmas and changes in the composition of the magma through mingling processes and progressive Crystallization. The zircon data show that the I-type Kosciusko tonalite was derived from a single source of crustal origin, whereas the S-type Berridale adamellite had two distinct sources including a significant I-type magma contribution. Complex Morphology and Hf isotope variations in zircon grains indicate a moderate contribution from a crustal component in the genesis of the I-type Dundee rhyodacite. The integration of data on Morphology, trace elements and Hf isotope variations in zircon populations provides a tool for the detailed analysis of the evolution of individual igneous rocks; it offers new insights into the contributions of different source rocks and the importance of magma mixing in granite petrogenesis. Such information is rarely obtainable from the analysis of bulk rocks.
W L Griffin - One of the best experts on this subject based on the ideXlab platform.
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zircon Crystal Morphology trace element signatures and hf isotope composition as a tool for petrogenetic modelling examples from eastern australian granitoids
Journal of Petrology, 2006Co-Authors: E A Belousova, W L Griffin, Suzanne Y OreillyAbstract:In situ laser ablation inductively coupled plasma mass spectrometry analysis of trace elements, U–Pb ages and Hf isotopic compositions of magmatic zircon from I- and S-type granitoids from the Lachlan Fold Belt (Berridale adamellite and Kosciusko tonalite) and New England Fold Belt (Dundee rhyodacite ignimbrite), Eastern Australia, is combined with detailed studies of Crystal Morphology to model petrogenetic processes. The presented examples demonstrate that changes in zircon Morphology, within single grains and between populations, generally correlate with changes in trace element and Hf-isotope signatures, reflecting the mixing of magmas and changes in the composition of the magma through mingling processes and progressive Crystallization. The zircon data show that the I-type Kosciusko tonalite was derived from a single source of crustal origin, whereas the S-type Berridale adamellite had two distinct sources including a significant I-type magma contribution. Complex Morphology and Hf isotope variations in zircon grains indicate a moderate contribution from a crustal component in the genesis of the I-type Dundee rhyodacite. The integration of data on Morphology, trace elements and Hf isotope variations in zircon populations provides a tool for the detailed analysis of the evolution of individual igneous rocks; it offers new insights into the contributions of different source rocks and the importance of magma mixing in granite petrogenesis. Such information is rarely obtainable from the analysis of bulk rocks.
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zircon Crystal Morphology trace element signatures and hf isotope composition as a tool for petrogenetic modelling examples from eastern australian granitoids
Journal of Petrology, 2006Co-Authors: E A Belousova, W L Griffin, Suzanne Y OreillyAbstract:In situ laser ablation inductively coupled plasma mass spectrometry analysis of trace elements, U–Pb ages and Hf isotopic compositions of magmatic zircon from I- and S-type granitoids from the Lachlan Fold Belt (Berridale adamellite and Kosciusko tonalite) and New England Fold Belt (Dundee rhyodacite ignimbrite), Eastern Australia, is combined with detailed studies of Crystal Morphology to model petrogenetic processes. The presented examples demonstrate that changes in zircon Morphology, within single grains and between populations, generally correlate with changes in trace element and Hf-isotope signatures, reflecting the mixing of magmas and changes in the composition of the magma through mingling processes and progressive Crystallization. The zircon data show that the I-type Kosciusko tonalite was derived from a single source of crustal origin, whereas the S-type Berridale adamellite had two distinct sources including a significant I-type magma contribution. Complex Morphology and Hf isotope variations in zircon grains indicate a moderate contribution from a crustal component in the genesis of the I-type Dundee rhyodacite. The integration of data on Morphology, trace elements and Hf isotope variations in zircon populations provides a tool for the detailed analysis of the evolution of individual igneous rocks; it offers new insights into the contributions of different source rocks and the importance of magma mixing in granite petrogenesis. Such information is rarely obtainable from the analysis of bulk rocks.
Rudolf Giovanoli - One of the best experts on this subject based on the ideXlab platform.
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citrate determines calcium oxalate Crystallization kinetics and Crystal Morphology studies in the presence of tamm horsfall protein of a healthy subject and a severely recurrent calcium stone former
Nephrology Dialysis Transplantation, 2000Co-Authors: B Hess, Samuel Jordi, L Zipperle, Emma Ettinger, Rudolf GiovanoliAbstract:BACKGROUND The aim of this study was to measure the effects of normal (nTHP) and abnormal stone former Tamm-Horsfall protein (SF-THP) on calcium oxalate (CaOx) nucleation and aggregation as well as on Crystal Morphology, in presence or absence of citrate. METHODS Nucleation and aggregation of CaOx Crystals from a supersaturated, stirred solution (200 mM NaCl, 10 mM Na-acetate, pH 5.70, 5 mM Ca and 0.5 mM Ox) were studied by spectrophotometric time-course measurements of OD at 620 nm (OD(620)). Measured parameters were induction time t(I) (time to induce formation of detectable particles), S(N), (slope of increase of OD(620), mainly due to Crystal nucleation), and S(A), (slope of decrease of OD(620) after equilibrium has been reached, due to Crystal aggregation). Effects of citrate, nTHP and SF-THP on these parameters were measured, and scanning electron microscopy (SEM) was performed. RESULTS At 1.5, 2.5 and 3.5 mM, citrate increased t(I) and inhibited Crystal nucleation (by 78-87%) as well as aggregation (by 63-70%), and smaller CaOx Crystals (length/width ratio 1.7+/-0.1) than under standard conditions (length/width 3.9+/-0.5) were visible (P<0.001). Normal THP at 30 and 40 mg/l inhibited Crystal nucleation and, more strongly, aggregation (inhibition 76-81%). SEM revealed a decrease in length/width ratio to 2.6+/-0.4 (P=0.051 vs standard conditions) and less aggregation than without nTHP. At all concentrations tested, SF-THP reduced t(I) (P=0.0001 vs standard conditions) and promoted aggregation (inhibition -48 to -33%); Crystals were elongated with a length/width ratio of 4.3+/-0.6 (P<0. 05 vs nTHP). When simultaneously present with nTHP, citrate enhanced the inhibitory effects of nTHP, producing the smallest (length/width 1.5+/-0.1) and least aggregated Crystals. Finally, 3.5 mM citrate turned promotory SF-THP into a Crystallization inhibitor with abundant small and clustered, but not aggregated Crystals. CONCLUSION Citrate appears to be the main determinant of CaOx Crystallization rates and Crystal Morphology in the presence of nTHP as well as SF-THP. Its effects appear to predominate over those of THP, since even promotory SF-THP is turned into a Crystallization inhibitor in the presence of citrate. This re-emphasizes at a morphological level what has been concluded from functional as well from clinical studies, namely that citrate is needed in urine at equimolar concentrations to calcium in order to prevent the formation of large Crystal aggregates in presence of abnormal THP.
Lin Zhang - One of the best experts on this subject based on the ideXlab platform.
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experimental study of the Crystal habit of high explosive octahydro 1 3 5 7 tetranitro 1 3 5 7 tetrazocine hmx in acetone and dimethyl sulfoxide
Crystal Growth & Design, 2020Co-Authors: Lin Zhang, Mi Yan, Wenlong Yin, Yu Liu, Song Zhao, Shiliang HuangAbstract:Crystal Morphology has a significant effect on the properties and applications of energetic materials (EMs). Here, we have combined the single-Crystal X-ray diffraction (SCXRD) and rotation imaging...