The Experts below are selected from a list of 7434 Experts worldwide ranked by ideXlab platform
Philippe Evon - One of the best experts on this subject based on the ideXlab platform.
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Twin-Screw Extrusion Process to Produce Renewable Fiberboards
Journal of visualized experiments : JoVE, 2021Co-Authors: Philippe Evon, Pierre-yves Pontalier, Laurent Labonne, Saif Ullah Khan, Pierre Ouagne, Antoine RouillyAbstract:A versatile twin-screw extrusion process to provide an efficient thermo-mechano-chemical pre-treatment on lignocellulosic biomass before using it as source of mechanical reinforcement in fully bio-based Fiberboards was developed. Various lignocellulosic crop by-products have already been successfully pre-treated through this process, e.g., cereal straws (especially rice), coriander straw, shives from oleaginous flax straw, and bark of both amaranth and sunflower stems. The extrusion process results in a marked increase in the average fiber aspect ratio, leading to improved mechanical properties of Fiberboards. The twin-screw extruder can also be fitted with a filtration module at the end of the barrel. The continuous extraction of various chemicals (e.g., free sugars, hemicelluloses, volatiles from essential oil fractions, etc.) from the lignocellulosic substrate, and the fiber refining can, therefore, be performed simultaneously. The extruder can also be used for its mixing ability: a natural binder (e.g., Organosolv lignins, protein-based oilcakes, starch, etc.) can be added to the refined fibers at the end of the screw profile. The obtained premix is ready to be molded through hot pressing, with the natural binder contributing to fiberboard cohesion. Such a combined process in a single extruder pass improves the production time, production cost, and may lead to reduction in plant production size. Because all the operations are performed in a single step, fiber morphology is better preserved, thanks to a reduced residence time of the material inside the extruder, resulting in enhanced material performances. Such one-step extrusion operation may be at the origin of a valuable industrial process intensification. Compared to commercial wood-based materials, these fully bio-based Fiberboards do not emit any formaldehyde, and they could find various applications, e.g., intermediate containers, furniture, domestic flooring, shelving, general construction, etc.
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VOC and carbonyl compound emissions of a fiberboard resulting from a coriander biorefinery: comparison with two commercial wood-based building materials
Environmental Science and Pollution Research, 2020Co-Authors: Valérie Simon, Evelien Uitterhaegen, Thierry Talou, Stéphane Ballas, Thierry Véronèse, Othmane Merah, Anaïs Robillard, Gérard Vilarem, Philippe EvonAbstract:Indoor air quality is a major public health issue. It is related to the choice of construction materials and associated with VOC emissions. Two wood-based commercial panels were tested: a medium-density fiberboard (MDF) and a chipboard (CH), and they were compared to a material produced from a coriander biorefinery (COR). Indicators chosen to compare the materials were physical properties (density, bending properties, surface hardness, thickness swelling, and water absorption) and VOC emissions. Emissions were evaluated in an environmental chamber at 23 °C, 31 °C, and 36 °C, and during 28 days. Carbonyl emissions on day 1 at 23 °C were 74, 146, and 35 μg m−2 h−1, respectively, for MDF, CH, and COR. Terpenic emissions were 12, 185, and 37 μg m−2 h−1, respectively. Higher temperature resulted in higher emissions which decreased over time, except for formaldehyde. VOC emissions depended largely on material and temperature. Formaldehyde emission was 300 to 600 times lower for coriander boards (< 0.2 μg m−2 h−1), making them significantly more environmentally friendly materials in comparison with MDF and chipboard. These results highlight the interest of coriander by-products as raw materials for producing Fiberboards with low impact on indoor air quality.
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Production of fiberboard from rice straw thermomechanical extrudates by thermopressing: influence of fiber morphology, water and lignin content
European Journal of Wood and Wood Products, 2019Co-Authors: Dyna Theng, Bunthan Ngo, Marc Delgado-aguilar, Laurent Labonne, Gerard Arbat, Pere Mutje, Philippe EvonAbstract:The objective of this study was to investigate the influence of fiber morphology and molding parameters on the mechanical and physical properties of Fiberboards made from rice straw. The rice straw was thermomechanically treated with a twin-screw extruder. Three parameters were investigated: the amount of water added at molding (0–20%), lignin content (0–25%), and the liquid/solid ratio used for extrudate production (0.33–1.07). A Doehlert experimental design was used to evaluate the effects of these factors on fiberboard properties. A liquid/solid ratio of 0.4 at extrudate production, the addition of 5% water at molding, and a lignin content of 8.9% were found to be optimal for bending properties. The fiberboard produced in these conditions had a density of 1414 kg/m^3 (i.e. the densest board). Maximum flexural strength and elastic modulus were 50.3 MPa and 8.6 GPa, respectively. A thickness swelling of 23.6% and 17.6% water absorption were observed. The statistical analysis suggested that a good compromise between density and flexural properties could be obtained with the addition of 0% water, a lignin content of 25% and a liquid/solid ratio of 0.33 at extrudate production. Polynomial models suggested that the Fiberboards produced in such conditions would have a maximum flexural strength of 50 MPa, an elastic modulus of 6.0 GPa, a density of 1102 kg/m^3, and a thickness swelling of 24%.
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impact of thermomechanical fiber pre treatment using twin screw extrusion on the production and properties of renewable binderless coriander Fiberboards
International Journal of Molecular Sciences, 2017Co-Authors: Evelien Uitterhaegen, Laurent Labonne, Thierry Talou, Stéphane Ballas, Thierry Véronèse, Othmane Merah, Philippe EvonAbstract:The aim of this study consisted of manufacturing renewable binderless Fiberboards from coriander straw and a deoiled coriander press cake, thus at the same time ensuring the valorization of crop residues and process by-products. The press cake acted as a natural binder inside the boards owing to the thermoplastic behavior of its protein fraction during thermopressing. The influence of different fiber-refining methods was evaluated and it was shown that a twin-screw extrusion treatment effectively improved fiber morphology and resulted in Fiberboards with enhanced performance as compared to a conventional grinding process. The best fiberboard was produced with extrusion-refined straw using a 0.4 liquid/solid (L/S) ratio and with 40% press cake addition. The water sensitivity of the boards was effectively reduced by 63% through the addition of an extrusion raw material premixing operation and thermal treatment of the panels at 200 °C, resulting in materials with good performance showing a flexural strength of 29 MPa and a thickness swelling of 24%. Produced without the use of any chemical adhesives, these Fiberboards could thus present viable, sustainable alternatives for current commercial wood-based materials such as oriented strand board, particleboard and medium-density fiberboard, with high cost-effectiveness.
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Manufacturing of renewable and biodegradable Fiberboards from cake generated during biorefinery of sunflower whole plant in twin-screw extruder: Influence of thermo-pressing conditions
Polymer Degradation and Stability, 2015Co-Authors: Philippe Evon, Virginie Vandenbossche, Luc RigalAbstract:The starting material used in this study was a cake generated during thermo-mechanical fractionation of sunflower (Helianthus annuus L.) whole plant in a twin-screw extruder. It was slightly deoiled (16.7% of oil in dry matter). Composed mainly of fibers and proteins, it could be considered as a natural composite and was processed successfully into Fiberboards by thermo-pressing. This study aimed to evaluate the influence of thermo-pressing conditions on mechanical and heat insulation properties of Fiberboards manufactured from this cake. All Fiberboards were cohesive, proteins and fibers acting respectively as binder and reinforcing fillers. Highest cake quantity (1000 mg/cm²) led to the highest breaking load (60.7 N) with a flexural strength at break quite low (2.9 MPa), lowest elastic modulus (216.6 MPa), and highest Charpy impact strength (6.5 kJ/m² for resilience). The increase of pressure applied during molding (from 320 to 360 kgf/cm²) led to an important increase of elastic modulus (from 352.6 to 728.6 MPa). Besides, fiberboard molded at 360 kgf/cm² was the most rigid of this study, and logically revealed the most important Shore D surface hardness (52.6°). Moreover, lowest molding time (60 s) led to the highest flexural strength at break (3.9 MPa). The low density of the Fiberboards (less than 0.97) involved promising heat insulation properties. Indeed, thermal conductivity of Fiberboards at 25 °C was low (from 103.5 to 135.7 mW/m K), and decreased with the increase of thickness. According to their mechanical and heat insulation properties, Fiberboards would be potentially usable as inter-layer sheets for pallets, for the manufacture of biodegradable containers (composters, crates for vegetable gardening) by assembly of Fiberboards, or for their heat insulation properties in building industry. Moreover, thermo-pressing was not only a molding operation. It also improved the oil extraction efficiency as a part of residual oil was expressed from cake during molding, and total oil yield reached 79.3% with a pressure applied of 360 kgf/cm².
Luc Rigal - One of the best experts on this subject based on the ideXlab platform.
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Manufacturing of renewable and biodegradable Fiberboards from cake generated during biorefinery of sunflower whole plant in twin-screw extruder: Influence of thermo-pressing conditions
Polymer Degradation and Stability, 2015Co-Authors: Philippe Evon, Virginie Vandenbossche, Luc RigalAbstract:The starting material used in this study was a cake generated during thermo-mechanical fractionation of sunflower (Helianthus annuus L.) whole plant in a twin-screw extruder. It was slightly deoiled (16.7% of oil in dry matter). Composed mainly of fibers and proteins, it could be considered as a natural composite and was processed successfully into Fiberboards by thermo-pressing. This study aimed to evaluate the influence of thermo-pressing conditions on mechanical and heat insulation properties of Fiberboards manufactured from this cake. All Fiberboards were cohesive, proteins and fibers acting respectively as binder and reinforcing fillers. Highest cake quantity (1000 mg/cm²) led to the highest breaking load (60.7 N) with a flexural strength at break quite low (2.9 MPa), lowest elastic modulus (216.6 MPa), and highest Charpy impact strength (6.5 kJ/m² for resilience). The increase of pressure applied during molding (from 320 to 360 kgf/cm²) led to an important increase of elastic modulus (from 352.6 to 728.6 MPa). Besides, fiberboard molded at 360 kgf/cm² was the most rigid of this study, and logically revealed the most important Shore D surface hardness (52.6°). Moreover, lowest molding time (60 s) led to the highest flexural strength at break (3.9 MPa). The low density of the Fiberboards (less than 0.97) involved promising heat insulation properties. Indeed, thermal conductivity of Fiberboards at 25 °C was low (from 103.5 to 135.7 mW/m K), and decreased with the increase of thickness. According to their mechanical and heat insulation properties, Fiberboards would be potentially usable as inter-layer sheets for pallets, for the manufacture of biodegradable containers (composters, crates for vegetable gardening) by assembly of Fiberboards, or for their heat insulation properties in building industry. Moreover, thermo-pressing was not only a molding operation. It also improved the oil extraction efficiency as a part of residual oil was expressed from cake during molding, and total oil yield reached 79.3% with a pressure applied of 360 kgf/cm².
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New thermal insulation Fiberboards from cake generated during biorefinery of sunflower whole plant in a twin-screw extruder
Industrial Crops and Products, 2015Co-Authors: Philippe Evon, Virginie Vandenbossche, Pierre-yves Pontalier, Luc RigalAbstract:The objective of this study was to manufacture new thermal insulation Fiberboards by thermo-pressing. The starting material was a slightly deoiled cake (17.6% oil content), generated during the biorefinery of sunflower (Helianthus annuus L.) whole plant in a co-rotating (Clextral BC 45, France) twin-screw extruder. All Fiberboards produced were cohesive mixtures of proteins and lignocellulosic fibers, acting respectively as binder and reinforcing fillers in what could be considered as a natural composite. The molding experiments were conducted using a 400 ton capacity heated hydraulic press (Pinette Emidecau Industries, France). The influence of molding conditions on board density, mechanical properties and heat insulation properties was examined. Molding conditions included mold temperature (140-200°C), pressure applied (150-250 kgf/cm²) and molding time (40-76 s), and these greatly affected board density and thus the mechanical and heat insulation properties. Board density increased with increasingly extreme molding conditions, rising from 500 to 858 kg/m³. The mechanical properties increased at the same time (from 52 to 660 kPa for flexural strength at break, from 5.9 to 49.4 MPa for elastic modulus, from 0.5 to 7.7 kJ/m² for Charpy impact strength, and from 19.2 to 47.1° for Shore D surface hardness). Conversely, heat insulation properties improved with decreasing board density, and the lowest thermal conductivity (88.5 mW/m K at 25°C) was obtained with the least dense fiberboard. The latter was produced with a 140°C mold temperature, a 150 kgf/cm² pressure applied and a 40 s molding time. A medium mold temperature (160°C) was needed to obtain a good compromise between mechanical properties (272 kPa for flexural strength at break, 26.3 MPa for elastic modulus, 3.2 kJ/m² for Charpy impact strength, and 37.3° for Shore D surface hardness), and heat insulation properties (99.5 mW/m K for thermal conductivity).The corresponding board density was medium (687 kg/m³). Because of their promising heat insulation properties, these new Fiberboards could be positioned on walls and ceilings for thermal insulation of buildings. The bulk cake also revealed very low thermal conductivity properties (only 65.6 mW/m K at 25°C) due to its very low bulk density (204 kg/m³). It could be used as loose fill in the attics of houses.
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New thermal insulation Fiberboards from cake generated during biorefinery of sunflower whole plant in a twin-screw extruder
Industrial Crops and Products, 2015Co-Authors: Philippe Evon, Virginie Vandenbossche, Pierre-yves Pontalier, Luc RigalAbstract:The objective of this study was to manufacture new thermal insulation Fiberboards by thermo-pressing. The starting material was a slightly deoiled cake (17.6% oil content), generated during the biorefinery of sunflower (Helianthus annuus L.) whole plant in a co-rotating (Clextral BC 45, France) twin-screw extruder. All Fiberboards produced were cohesive mixtures of proteins and lignocellulosic fibers, acting respectively as binder and reinforcing fillers in what could be considered as a natural composite. The molding experiments were conducted using a 400 ton capacity heated hydraulic press (Pinette Emidecau Industries, France). The influence of molding conditions on board density, mechanical properties and heat insulation properties was examined. Molding conditions included mold temperature (140-200°C), pressure applied (150-250 kgf/cm²) and molding time (40-76 s), and these greatly affected board density and thus the mechanical and heat insulation properties. Board density increased with increasingly extreme molding conditions, rising from 500 to 858 kg/m³. The mechanical properties increased at the same time (from 52 to 660 kPa for flexural strength at break, from 5.9 to 49.4 MPa for elastic modulus, from 0.5 to 7.7 kJ/m² for Charpy impact strength, and from 19.2 to 47.1° for Shore D surface hardness). Conversely, heat insulation properties improved with decreasing board density, and the lowest thermal conductivity (88.5 mW/m K at 25°C) was obtained with the least dense fiberboard. The latter was produced with a 140°C mold temperature, a 150 kgf/cm² pressure applied and a 40 s molding time. A medium mold temperature (160°C) was needed to obtain a good compromise between mechanical properties (272 kPa for flexural strength at break, 26.3 MPa for elastic modulus, 3.2 kJ/m² for Charpy impact strength, and 37.3° for Shore D surface hardness), and heat insulation properties (99.5 mW/m K for thermal conductivity).The corresponding board density was medium (687 kg/m³). Because of their promising heat insulation properties, these new Fiberboards could be positioned on walls and ceilings for thermal insulation of buildings. The bulk cake also revealed very low thermal conductivity properties (only 65.6 mW/m K at 25°C) due to its very low bulk density (204 kg/m³). It could be used as loose fill in the attics of houses.
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New renewable and biodegradable Fiberboards from a coriander press cake
2015Co-Authors: Evelien Uitterhaegen, Thierry Talou, Othmane Merah, Luc Rigal, Quang Hung Nguyen, Chris V. Stevens, Philippe EvonAbstract:This study aimed to evaluate the influence of the thermo-pressing conditions (mold temperature, applied pressure and molding time) on the mechanical properties, the thickness swelling and the water absorption of Fiberboards made from a coriander press cake produced in a single-screw extruder. In regard to the mechanical properties of the optimal board and its water-sensitivity, such a fiberboard would be applicable as inter-layer sheets for pallets, for the manufacture of containers or furniture, or in the building trade (floor under-layers, interior partitions or ceiling tiles). Moreover, thermo-pressing not only produces cohesive Fiberboards, but also significantly increases the oil extraction efficiency.
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New insulation Fiberboards from sunflower cake with improved thermal and mechanical properties
2014Co-Authors: Philippe Evon, Laurent Labonne, Justine Vinet, Matthieu Rigal, Luc RigalAbstract:New insulation Fiberboards from sunflower cake with improved thermal and mechanical properties were produced by pressing at ambient temperature. Best compromise between mechanical and heat insulation properties (λ = 77.6 mW/m K at 25°C) was a starch-based board with 20% binder content. Because of its promising heat insulation properties, this new fiberboard could be positioned on walls and ceilings for thermal insulation of buildings. The bulk cake was an even better insulation material (only 62.0 mW/m K for thermal conductivity at 25°C): usable as loose fill in the attics of houses.
Joan Salvadó - One of the best experts on this subject based on the ideXlab platform.
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All-lignocellulosic Fiberboard from Steam Exploded Arundo Donax L.
MDPI AG, 2018Co-Authors: Diego Ramos, Nour-eddine El Mansouri, Francesc Ferrando, Joan SalvadóAbstract:This paper explores the possibility of producing all-lignocellulosic Fiberboards from Arundo donax L. as a source of lignocellulosic fibers with no synthetic binders. This raw material was steam exploded with a thermomechanical aqueous vapor process in a batch reactor. The Arundo donax raw material and its obtained pulp were characterized in terms of chemical composition and the results were compared to other lignocellulosic materials. The chemical composition of steam exploded Arundo fibers showed high cellulose and a moderate lignin content suggesting it was a good raw material for fiberboard production. The all-lignocellulosic Fiberboards were produced on laboratory scale; using the steam exploded Arundo donax by means of a wet process. The effects of pressing pressure on physical and mechanical properties were evaluated and the conditions that optimize the responses were found. The analyzed properties were density (d); water absorption (WA); thickness swelling (TS); modulus of elasticity (MOE); modulus of rupture (MOR); and internal bond strength (IB). The tested levels of the pressing pressure range from 0.35 to 15 MPa. The optimum IB; MOE; MOR; WA and TS were 1.28 MPa, 7439 MPa, 40.4 MPa, 17.6% and 13.3%, respectively. The obtained Fiberboards were of very good quality and more than satisfy the requirements of the relevant standard specifications
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feasibility of incorporating treated lignins in Fiberboards made from agricultural waste
Waste Management, 2012Co-Authors: Camilo Mancera, Nour-eddine El Mansouri, Maria Angels Pelach, Ferrando Francesc, Joan SalvadóAbstract:This paper studies the feasibility of incorporating treated lignins in Fiberboards made from Vitis vinifera as an agricultural waste. The treated lignins are the purified Kraft lignin and the alkaline hydrolyzed Kraft lignin. V. vinifera raw material and its fibers were characterized in terms of chemical composition and the results were compared to other biomass species. The chemical composition of treated lignins shows that they have high purity compared to the lignin raw material. The lignin-V. vinifera fibreboards were produced on laboratory scale by adding powdered treated lignins to the material that had previously been steam exploded. Some of the important properties of fibreboards prepared using the treated lignins as natural adhesives were evaluated. These properties were density, thickness swelling, water absorption, modulus of elasticity, modulus of rupture, internal bond strength. The explored levels of treated lignins vary from 5% to 20%. The results showed that binderless fibreboards, fibreboards made from V. vinifera fibers and alkaline hydrolyzed Kraft lignin have weaker mechanical properties. However, the fibreboards obtained using purified Kraft lignin have good mechanical and water resistance properties which satisfy the requirements of the relevant standards specifications.
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THE SUITABILITY OF STEAM EXPLODED VITIS VINIFERA AND ALKALINE LIGNIN FOR THE MANUFACTURE OF FIBERBOARD
Bioresources, 2011Co-Authors: Camilo Mancera, Nour-eddine El Mansouri, Francesc Ferrando, Joan SalvadóAbstract:The main objective of this study was to explore the suitability of Vitis vinifera as a raw material and alkaline lignin as a natural binder for fiberboard manufacturing. In the first step, Vitis vinifera was steam- exploded through a thermo-mechanical vapor process in a batch reactor, and the obtained pulp was dried, ground, and pressed to produce the boards. The effects of pretreatment factors and pressing conditions on the chemical composition of the fibers and the physico-mechanical properties of binderless Fiberboards were evaluated, and the conditions that optimize these properties were found. A response surface method based on a central composite design and multiple-response optimization was used. The variables studied and their respective variation ranges were: pretreatment temperature (Tr: 190-210oC), pretreatment time (tr: 5-10 min), pressing temperature (Tp: 190-210oC), pressing pressure (Pp: 8-16MPa), and pressing time (tp: 3-7min). The results of the optimization step show that binderless Fiberboards have good water resistance and weaker mechanical properties. In the second step, Fiberboards based on alkaline lignin and Vitis vinifera pulp produced at the optimal conditions determined for binderless Fiberboards were prepared and their physico-mechanical properties were tested. Our results show that the addition of about 15% alkaline lignin leads to the production of Fiberboards that fully meet the requirements of the relevant standard specifications.
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THE EFFECT OF LIGNIN AS A NATURAL ADHESIVE ON THE PHYSICO-MECHANICAL PROPERTIES OF VITIS VINIFERA Fiberboards
Bioresources, 2011Co-Authors: Camilo Mancera, Fabiola Vilaseca, Nour-eddine El Mansouri, Francesc Ferrando, Joan SalvadóAbstract:Lignin was used as a natural adhesive to manufacture Vitis vinifera Fiberboards. The Fiberboards were produced at laboratory scale by adding powdered lignin to material that had previously been steam-exploded under optimized pretreatment and pressing conditions. The kraft lignin used was washed several times with an acidic solution to eliminate any contaminants and low molecular weight compounds. This research studied the effects of amounts of lignin ranging from 5% to 20% on the properties of Vitis vinifera Fiberboards. The fiberboard properties evaluated were density, water resistance in terms of thickness swelling, water absorption, and the mechanical properties in terms of modulus of rupture, modulus of elasticity, and internal bond. Results showed that Fiberboards made from Vitis vinifera without lignin addition had weaker mechanical properties. However, the Fiberboards obtained using acid-washed kraft lignin as a natural adhesive had good mechanical and water resistance properties that fully satisfied the relevant standard specifications.
Virginie Vandenbossche - One of the best experts on this subject based on the ideXlab platform.
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Manufacturing of renewable and biodegradable Fiberboards from cake generated during biorefinery of sunflower whole plant in twin-screw extruder: Influence of thermo-pressing conditions
Polymer Degradation and Stability, 2015Co-Authors: Philippe Evon, Virginie Vandenbossche, Luc RigalAbstract:The starting material used in this study was a cake generated during thermo-mechanical fractionation of sunflower (Helianthus annuus L.) whole plant in a twin-screw extruder. It was slightly deoiled (16.7% of oil in dry matter). Composed mainly of fibers and proteins, it could be considered as a natural composite and was processed successfully into Fiberboards by thermo-pressing. This study aimed to evaluate the influence of thermo-pressing conditions on mechanical and heat insulation properties of Fiberboards manufactured from this cake. All Fiberboards were cohesive, proteins and fibers acting respectively as binder and reinforcing fillers. Highest cake quantity (1000 mg/cm²) led to the highest breaking load (60.7 N) with a flexural strength at break quite low (2.9 MPa), lowest elastic modulus (216.6 MPa), and highest Charpy impact strength (6.5 kJ/m² for resilience). The increase of pressure applied during molding (from 320 to 360 kgf/cm²) led to an important increase of elastic modulus (from 352.6 to 728.6 MPa). Besides, fiberboard molded at 360 kgf/cm² was the most rigid of this study, and logically revealed the most important Shore D surface hardness (52.6°). Moreover, lowest molding time (60 s) led to the highest flexural strength at break (3.9 MPa). The low density of the Fiberboards (less than 0.97) involved promising heat insulation properties. Indeed, thermal conductivity of Fiberboards at 25 °C was low (from 103.5 to 135.7 mW/m K), and decreased with the increase of thickness. According to their mechanical and heat insulation properties, Fiberboards would be potentially usable as inter-layer sheets for pallets, for the manufacture of biodegradable containers (composters, crates for vegetable gardening) by assembly of Fiberboards, or for their heat insulation properties in building industry. Moreover, thermo-pressing was not only a molding operation. It also improved the oil extraction efficiency as a part of residual oil was expressed from cake during molding, and total oil yield reached 79.3% with a pressure applied of 360 kgf/cm².
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New thermal insulation Fiberboards from cake generated during biorefinery of sunflower whole plant in a twin-screw extruder
Industrial Crops and Products, 2015Co-Authors: Philippe Evon, Virginie Vandenbossche, Pierre-yves Pontalier, Luc RigalAbstract:The objective of this study was to manufacture new thermal insulation Fiberboards by thermo-pressing. The starting material was a slightly deoiled cake (17.6% oil content), generated during the biorefinery of sunflower (Helianthus annuus L.) whole plant in a co-rotating (Clextral BC 45, France) twin-screw extruder. All Fiberboards produced were cohesive mixtures of proteins and lignocellulosic fibers, acting respectively as binder and reinforcing fillers in what could be considered as a natural composite. The molding experiments were conducted using a 400 ton capacity heated hydraulic press (Pinette Emidecau Industries, France). The influence of molding conditions on board density, mechanical properties and heat insulation properties was examined. Molding conditions included mold temperature (140-200°C), pressure applied (150-250 kgf/cm²) and molding time (40-76 s), and these greatly affected board density and thus the mechanical and heat insulation properties. Board density increased with increasingly extreme molding conditions, rising from 500 to 858 kg/m³. The mechanical properties increased at the same time (from 52 to 660 kPa for flexural strength at break, from 5.9 to 49.4 MPa for elastic modulus, from 0.5 to 7.7 kJ/m² for Charpy impact strength, and from 19.2 to 47.1° for Shore D surface hardness). Conversely, heat insulation properties improved with decreasing board density, and the lowest thermal conductivity (88.5 mW/m K at 25°C) was obtained with the least dense fiberboard. The latter was produced with a 140°C mold temperature, a 150 kgf/cm² pressure applied and a 40 s molding time. A medium mold temperature (160°C) was needed to obtain a good compromise between mechanical properties (272 kPa for flexural strength at break, 26.3 MPa for elastic modulus, 3.2 kJ/m² for Charpy impact strength, and 37.3° for Shore D surface hardness), and heat insulation properties (99.5 mW/m K for thermal conductivity).The corresponding board density was medium (687 kg/m³). Because of their promising heat insulation properties, these new Fiberboards could be positioned on walls and ceilings for thermal insulation of buildings. The bulk cake also revealed very low thermal conductivity properties (only 65.6 mW/m K at 25°C) due to its very low bulk density (204 kg/m³). It could be used as loose fill in the attics of houses.
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New thermal insulation Fiberboards from cake generated during biorefinery of sunflower whole plant in a twin-screw extruder
Industrial Crops and Products, 2015Co-Authors: Philippe Evon, Virginie Vandenbossche, Pierre-yves Pontalier, Luc RigalAbstract:The objective of this study was to manufacture new thermal insulation Fiberboards by thermo-pressing. The starting material was a slightly deoiled cake (17.6% oil content), generated during the biorefinery of sunflower (Helianthus annuus L.) whole plant in a co-rotating (Clextral BC 45, France) twin-screw extruder. All Fiberboards produced were cohesive mixtures of proteins and lignocellulosic fibers, acting respectively as binder and reinforcing fillers in what could be considered as a natural composite. The molding experiments were conducted using a 400 ton capacity heated hydraulic press (Pinette Emidecau Industries, France). The influence of molding conditions on board density, mechanical properties and heat insulation properties was examined. Molding conditions included mold temperature (140-200°C), pressure applied (150-250 kgf/cm²) and molding time (40-76 s), and these greatly affected board density and thus the mechanical and heat insulation properties. Board density increased with increasingly extreme molding conditions, rising from 500 to 858 kg/m³. The mechanical properties increased at the same time (from 52 to 660 kPa for flexural strength at break, from 5.9 to 49.4 MPa for elastic modulus, from 0.5 to 7.7 kJ/m² for Charpy impact strength, and from 19.2 to 47.1° for Shore D surface hardness). Conversely, heat insulation properties improved with decreasing board density, and the lowest thermal conductivity (88.5 mW/m K at 25°C) was obtained with the least dense fiberboard. The latter was produced with a 140°C mold temperature, a 150 kgf/cm² pressure applied and a 40 s molding time. A medium mold temperature (160°C) was needed to obtain a good compromise between mechanical properties (272 kPa for flexural strength at break, 26.3 MPa for elastic modulus, 3.2 kJ/m² for Charpy impact strength, and 37.3° for Shore D surface hardness), and heat insulation properties (99.5 mW/m K for thermal conductivity).The corresponding board density was medium (687 kg/m³). Because of their promising heat insulation properties, these new Fiberboards could be positioned on walls and ceilings for thermal insulation of buildings. The bulk cake also revealed very low thermal conductivity properties (only 65.6 mW/m K at 25°C) due to its very low bulk density (204 kg/m³). It could be used as loose fill in the attics of houses.
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Thermo-pressing of cake meal from sunflower whole plant, one only operation for two actions: expression of residual oil and molding of biodegradable agromaterials
2012Co-Authors: Philippe Evon, Virginie Vandenbossche, Pierre-yves Pontalier, Luc RigalAbstract:The starting material used in this study was a cake generated during thermo-mechanical fractionation of sunflower (Helianthus annuus L.) whole plant in a Clextral BC 45 (France) twin-screw extruder. It was slightly deoiled (17.6% dry matter for residual oil content), leading to an oil extraction yield of 46.1% (yield based on the residual oil content in cake). As it was a mixture of fibers and proteins, it could be considered as a natural composite that was processed successfully into Fiberboards by thermo-pressing. This study aimed to evaluate the influence of thermo-pressing conditions on oil expression yield during molding and on flexural properties of Fiberboards manufactured from this cake. An experimental design with three variables was realized: from 250 to 500 kgf/cm² for pressure applied (in 5 levels), from 60 to 300 s for molding time (in 7 levels), and from 600 to 1200 mg/cm² for cake quantity (in 3 levels). Temperature of the aluminium mold positioned between the two plates of the heated hydraulic press (PEI, France) with 400 tons capacity was 200°C. All Fiberboards were cohesive. As an internal binder, proteins ensured the agromaterial cohesion, and fibers entanglement also acted like reinforcement. Thermo-pressing was not only a molding operation. It also consisted in increasing the oil extraction efficiency. Oil expression yield during molding increased with the increase of pressure applied, and especially with the increase of molding time. At the same time, it was not so much influenced by the modification of cake quantity. Highest oil expression yield was 58.8% in proportion to the oil that the cake contained, leading to a total oil yield (oil extracted by water in twin-screw extruder, and oil expressed during molding) of 77.8% in proportion to the oil that the sunflower whole plant contained. It was associated with the next thermo-pressing conditions: 469 kgf/cm² for pressure applied, 300 s for molding time, and 697 mg/cm² for cake quantity. Flexural properties of the corresponding fiberboard were 8.1 MPa for flexural strength at break, and 1778 MPa for elastic modulus. Its thickness was 5.40 mm, leading to a mean apparent density of 1.25. Such flexural strength at break was a bit lower (-25%) than the one of the most resistant fiberboard (10.8 MPa), manufactured from the next thermo-pressing conditions: 250 kgf/cm² for pressure applied, 300 s for molding time, and 807 mg/cm² for cake quantity. For such conditions, oil expression yield was 48.0% in proportion to the oil that the cake contained, leading to a total oil yield close (-8%) to the highest yield obtained (71.9% in proportion to the oil that the sunflower whole plant contained instead of 77.8%). Thermo-pressing of cake from sunflower whole plant led to two actions in a single step: the expression of part of residual oil in cake that contributed to the improvement of the oil extraction efficiency, and the molding of biodegradable Fiberboards. Their flexural properties were promising. Moreover, because residual oil content in Fiberboards was at least 8.0% dry matter, they were not too water-sensitive (i.e. more durable than other thermo-pressed agromaterials). Such Fiberboards were value-added agromaterials that may have direct industrial applications. Indeed, they would be potentially usable as inter-layer sheets for pallets, for the manufacturing of biodegradable containers (composters, crates for vegetable gardening), or for their heat insulation properties in building trade.
Pierre-yves Pontalier - One of the best experts on this subject based on the ideXlab platform.
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Twin-Screw Extrusion Process to Produce Renewable Fiberboards
Journal of visualized experiments : JoVE, 2021Co-Authors: Philippe Evon, Pierre-yves Pontalier, Laurent Labonne, Saif Ullah Khan, Pierre Ouagne, Antoine RouillyAbstract:A versatile twin-screw extrusion process to provide an efficient thermo-mechano-chemical pre-treatment on lignocellulosic biomass before using it as source of mechanical reinforcement in fully bio-based Fiberboards was developed. Various lignocellulosic crop by-products have already been successfully pre-treated through this process, e.g., cereal straws (especially rice), coriander straw, shives from oleaginous flax straw, and bark of both amaranth and sunflower stems. The extrusion process results in a marked increase in the average fiber aspect ratio, leading to improved mechanical properties of Fiberboards. The twin-screw extruder can also be fitted with a filtration module at the end of the barrel. The continuous extraction of various chemicals (e.g., free sugars, hemicelluloses, volatiles from essential oil fractions, etc.) from the lignocellulosic substrate, and the fiber refining can, therefore, be performed simultaneously. The extruder can also be used for its mixing ability: a natural binder (e.g., Organosolv lignins, protein-based oilcakes, starch, etc.) can be added to the refined fibers at the end of the screw profile. The obtained premix is ready to be molded through hot pressing, with the natural binder contributing to fiberboard cohesion. Such a combined process in a single extruder pass improves the production time, production cost, and may lead to reduction in plant production size. Because all the operations are performed in a single step, fiber morphology is better preserved, thanks to a reduced residence time of the material inside the extruder, resulting in enhanced material performances. Such one-step extrusion operation may be at the origin of a valuable industrial process intensification. Compared to commercial wood-based materials, these fully bio-based Fiberboards do not emit any formaldehyde, and they could find various applications, e.g., intermediate containers, furniture, domestic flooring, shelving, general construction, etc.
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New thermal insulation Fiberboards from cake generated during biorefinery of sunflower whole plant in a twin-screw extruder
Industrial Crops and Products, 2015Co-Authors: Philippe Evon, Virginie Vandenbossche, Pierre-yves Pontalier, Luc RigalAbstract:The objective of this study was to manufacture new thermal insulation Fiberboards by thermo-pressing. The starting material was a slightly deoiled cake (17.6% oil content), generated during the biorefinery of sunflower (Helianthus annuus L.) whole plant in a co-rotating (Clextral BC 45, France) twin-screw extruder. All Fiberboards produced were cohesive mixtures of proteins and lignocellulosic fibers, acting respectively as binder and reinforcing fillers in what could be considered as a natural composite. The molding experiments were conducted using a 400 ton capacity heated hydraulic press (Pinette Emidecau Industries, France). The influence of molding conditions on board density, mechanical properties and heat insulation properties was examined. Molding conditions included mold temperature (140-200°C), pressure applied (150-250 kgf/cm²) and molding time (40-76 s), and these greatly affected board density and thus the mechanical and heat insulation properties. Board density increased with increasingly extreme molding conditions, rising from 500 to 858 kg/m³. The mechanical properties increased at the same time (from 52 to 660 kPa for flexural strength at break, from 5.9 to 49.4 MPa for elastic modulus, from 0.5 to 7.7 kJ/m² for Charpy impact strength, and from 19.2 to 47.1° for Shore D surface hardness). Conversely, heat insulation properties improved with decreasing board density, and the lowest thermal conductivity (88.5 mW/m K at 25°C) was obtained with the least dense fiberboard. The latter was produced with a 140°C mold temperature, a 150 kgf/cm² pressure applied and a 40 s molding time. A medium mold temperature (160°C) was needed to obtain a good compromise between mechanical properties (272 kPa for flexural strength at break, 26.3 MPa for elastic modulus, 3.2 kJ/m² for Charpy impact strength, and 37.3° for Shore D surface hardness), and heat insulation properties (99.5 mW/m K for thermal conductivity).The corresponding board density was medium (687 kg/m³). Because of their promising heat insulation properties, these new Fiberboards could be positioned on walls and ceilings for thermal insulation of buildings. The bulk cake also revealed very low thermal conductivity properties (only 65.6 mW/m K at 25°C) due to its very low bulk density (204 kg/m³). It could be used as loose fill in the attics of houses.
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New thermal insulation Fiberboards from cake generated during biorefinery of sunflower whole plant in a twin-screw extruder
Industrial Crops and Products, 2015Co-Authors: Philippe Evon, Virginie Vandenbossche, Pierre-yves Pontalier, Luc RigalAbstract:The objective of this study was to manufacture new thermal insulation Fiberboards by thermo-pressing. The starting material was a slightly deoiled cake (17.6% oil content), generated during the biorefinery of sunflower (Helianthus annuus L.) whole plant in a co-rotating (Clextral BC 45, France) twin-screw extruder. All Fiberboards produced were cohesive mixtures of proteins and lignocellulosic fibers, acting respectively as binder and reinforcing fillers in what could be considered as a natural composite. The molding experiments were conducted using a 400 ton capacity heated hydraulic press (Pinette Emidecau Industries, France). The influence of molding conditions on board density, mechanical properties and heat insulation properties was examined. Molding conditions included mold temperature (140-200°C), pressure applied (150-250 kgf/cm²) and molding time (40-76 s), and these greatly affected board density and thus the mechanical and heat insulation properties. Board density increased with increasingly extreme molding conditions, rising from 500 to 858 kg/m³. The mechanical properties increased at the same time (from 52 to 660 kPa for flexural strength at break, from 5.9 to 49.4 MPa for elastic modulus, from 0.5 to 7.7 kJ/m² for Charpy impact strength, and from 19.2 to 47.1° for Shore D surface hardness). Conversely, heat insulation properties improved with decreasing board density, and the lowest thermal conductivity (88.5 mW/m K at 25°C) was obtained with the least dense fiberboard. The latter was produced with a 140°C mold temperature, a 150 kgf/cm² pressure applied and a 40 s molding time. A medium mold temperature (160°C) was needed to obtain a good compromise between mechanical properties (272 kPa for flexural strength at break, 26.3 MPa for elastic modulus, 3.2 kJ/m² for Charpy impact strength, and 37.3° for Shore D surface hardness), and heat insulation properties (99.5 mW/m K for thermal conductivity).The corresponding board density was medium (687 kg/m³). Because of their promising heat insulation properties, these new Fiberboards could be positioned on walls and ceilings for thermal insulation of buildings. The bulk cake also revealed very low thermal conductivity properties (only 65.6 mW/m K at 25°C) due to its very low bulk density (204 kg/m³). It could be used as loose fill in the attics of houses.
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Thermo-pressing of cake meal from sunflower whole plant, one only operation for two actions: expression of residual oil and molding of biodegradable agromaterials
2012Co-Authors: Philippe Evon, Virginie Vandenbossche, Pierre-yves Pontalier, Luc RigalAbstract:The starting material used in this study was a cake generated during thermo-mechanical fractionation of sunflower (Helianthus annuus L.) whole plant in a Clextral BC 45 (France) twin-screw extruder. It was slightly deoiled (17.6% dry matter for residual oil content), leading to an oil extraction yield of 46.1% (yield based on the residual oil content in cake). As it was a mixture of fibers and proteins, it could be considered as a natural composite that was processed successfully into Fiberboards by thermo-pressing. This study aimed to evaluate the influence of thermo-pressing conditions on oil expression yield during molding and on flexural properties of Fiberboards manufactured from this cake. An experimental design with three variables was realized: from 250 to 500 kgf/cm² for pressure applied (in 5 levels), from 60 to 300 s for molding time (in 7 levels), and from 600 to 1200 mg/cm² for cake quantity (in 3 levels). Temperature of the aluminium mold positioned between the two plates of the heated hydraulic press (PEI, France) with 400 tons capacity was 200°C. All Fiberboards were cohesive. As an internal binder, proteins ensured the agromaterial cohesion, and fibers entanglement also acted like reinforcement. Thermo-pressing was not only a molding operation. It also consisted in increasing the oil extraction efficiency. Oil expression yield during molding increased with the increase of pressure applied, and especially with the increase of molding time. At the same time, it was not so much influenced by the modification of cake quantity. Highest oil expression yield was 58.8% in proportion to the oil that the cake contained, leading to a total oil yield (oil extracted by water in twin-screw extruder, and oil expressed during molding) of 77.8% in proportion to the oil that the sunflower whole plant contained. It was associated with the next thermo-pressing conditions: 469 kgf/cm² for pressure applied, 300 s for molding time, and 697 mg/cm² for cake quantity. Flexural properties of the corresponding fiberboard were 8.1 MPa for flexural strength at break, and 1778 MPa for elastic modulus. Its thickness was 5.40 mm, leading to a mean apparent density of 1.25. Such flexural strength at break was a bit lower (-25%) than the one of the most resistant fiberboard (10.8 MPa), manufactured from the next thermo-pressing conditions: 250 kgf/cm² for pressure applied, 300 s for molding time, and 807 mg/cm² for cake quantity. For such conditions, oil expression yield was 48.0% in proportion to the oil that the cake contained, leading to a total oil yield close (-8%) to the highest yield obtained (71.9% in proportion to the oil that the sunflower whole plant contained instead of 77.8%). Thermo-pressing of cake from sunflower whole plant led to two actions in a single step: the expression of part of residual oil in cake that contributed to the improvement of the oil extraction efficiency, and the molding of biodegradable Fiberboards. Their flexural properties were promising. Moreover, because residual oil content in Fiberboards was at least 8.0% dry matter, they were not too water-sensitive (i.e. more durable than other thermo-pressed agromaterials). Such Fiberboards were value-added agromaterials that may have direct industrial applications. Indeed, they would be potentially usable as inter-layer sheets for pallets, for the manufacturing of biodegradable containers (composters, crates for vegetable gardening), or for their heat insulation properties in building trade.