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  • visible light induced Metal free allylic oxidation utilizing a coupled photocatalytic system of g c3n4 and n hydroxy compounds
    Advanced Synthesis & Catalysis, 2011
    Co-Authors: Pengfei Zhang, Yong Wang, Congmin Wang, Markus Antonietti, Haoran Li
    Abstract:

    Graphitic carbon nitride (g-C 3 N 4 ) and N-hydroxy compounds can function as a non-Metal photocatalytic system to activate O 2 for the selective allylic oxidation under mild conditions, avoiding the employment of any Metal Derivative or organic oxidizing agents. Interestingly, the novel photocatalytic system affords a remarkably high selectivity towards the formation of aldehydes, especially in the oxidation of toluene. By combining the unique nature of g-C 3 N 4 (surface basicity, semiconductor features, high stability) and the remarkable catalytic oxidation reactivity of nitroxyl radicals, this photocatalytic system opens up a mild and efficent access for C―H bond activation.