The Experts below are selected from a list of 360 Experts worldwide ranked by ideXlab platform
Huai Yang - One of the best experts on this subject based on the ideXlab platform.
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a facile route towards controllable electric optical performance of polymer dispersed Liquid Crystal via the implantation of Liquid Crystalline epoxy network in conventional resin
Polymer, 2019Co-Authors: Wenbo Shen, Zhou Yang, Lanying Zhang, Ling Wang, Gang Chen, Huai YangAbstract:Abstract A Liquid Crystalline epoxide was synthesized and its curing reactivity was compared with that of the conventional epoxy monomers. By utilizing the difference in curing reactivity between the Liquid Crystalline epoxide and non-Liquid Crystalline epoxy monomers, a coexistent system of Polymer-Dispersed and polymer-stabilized Liquid Crystal (LC) in the intelligent films can be obtained by two-step thermal curing method. If the later curing process was undertaken under an external electric field, the ordered microstructure of Liquid Crystalline epoxy polymer (LCEP) network can be implanted into the conventional epoxy resin. The competition of the anchoring effect on the LC molecules from the LCEP network and the conventional epoxy resin matrix was crucial to the electro-optical performance of the films. Moreover, the performance of the films can be adjusted by controlling the content of Liquid Crystalline epoxide and the external electric field applied during later curing. This approach can provide a facile route to regulate the electric-optical performance of Polymer-Dispersed Liquid Crystal films for practical applications.
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effects of crosslinking agent diluents thiol on morphology of the polymer matrix and electro optical properties of polymer dispersed Liquid Crystal
Liquid Crystals, 2018Co-Authors: Yi Zhang, Cuihong Zhang, Huai Yang, Zhou Yang, Lanying Zhang, Le Zhou, Jie Yang, Jiazhen Zhang, Mingtan Hai, Siquan ZhuAbstract:To study effects of the crosslinking agent/diluents/thiol on morphology of the polymer matrix and the electro-optical properties of Polymer-Dispersed Liquid Crystal (PDLC) films, samples were prepa...
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effects of functionality of thiol monomer on electro optical properties of polymer dispersed Liquid Crystal films
Liquid Crystals, 2017Co-Authors: Cuihong Zhang, Jiumei Xiao, Hangjun Ding, Fasheng Li, Haifeng Yu, Zhou Yang, Huai YangAbstract:ABSTRACTIn this paper, Polymer-Dispersed Liquid Crystal (PDLC) films which based on the acrylate and the thiol monomers were first prepared by ultraviolet-initiated polymerisation. The electro-optical properties and morphologies of the PDLC films were systematically investigated. The functionality of thiol monomers and their feed ratio showed great influence on the properties of the fabricated PDLC films because of the existence of competition between thiol–acrylate reaction and acrylate monomer polymerisation reaction. This made the polymer network and electro-optical properties of the PDLC films easily tunable by the introduction of the thiol monomers. When added four-functional thiol monomer PETMP with appropriate concentration into the PDLC system, lower driven voltage and higher contrast ratio were achieved.
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preparation and electro optical properties of polymer dispersed Liquid Crystal films with relatively low Liquid Crystal content
Polymers for Advanced Technologies, 2013Co-Authors: Cuihong Zhang, Huai Yang, Ping Song, Dongrui Wang, Hui Cao, Chaoyong YangAbstract:In this paper, polymer dispersed Liquid Crystals (PDLC) films with LC content as low as 40 wt% were prepared, and the electro-optical properties were carefully investigated. To accomplish this, different (meth)acrylate copolymerizaiton monomers have been used. The electro-optical properties and morphologies of the PDLC films were strongly influenced by the chemical structure of copolymerization monomers (hydroxypropyl methacrylate (HPMA), glycidyl methacrylate, hydroxypropyl acrylate) and their feed ratio. Lower driven voltage and higher contrast ratio were achieved when the PDLC films showed a morphology with suitably LC domain size. At high HPMA content, a thin polymer film was formed on the surface of PDLC samples, which is beneficial to decrease the total LC content in PDLC devices. Copyright © 2013 John Wiley & Sons, Ltd.
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effects of monomer structure on the morphology of polymer networks and the electro optical properties of polymer dispersed Liquid Crystal films
Liquid Crystals, 2012Co-Authors: Ping Song, Huai YangAbstract:Polymer-Dispersed Liquid Crystal (PDLC) films were prepared by photochemical polymerisation with a series of (meth)acrylate monomers. The effects of monomer structure on the morphology of polymer networks in the PDLC films were studied. The acrylate monomers without sidegroup chain formed uniform polymer networks. The methacrylate monomers with methyl as their sidegroup chains formed lace-like networks. The size of the LC droplets increased with increasing the length of the flexible chain of both methacrylate and acrylate monomers. Meanwhile, the effects of the morphology of the polymer network on the electro-optical properties of PDLC films were also investigated.
Gregory P. Crawford - One of the best experts on this subject based on the ideXlab platform.
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electrically switchable mesoscale penrose quasiCrystal structure
Applied Physics Letters, 2005Co-Authors: Suraj P Gorkhali, Gregory P. CrawfordAbstract:We present the design, fabrication, and electro-optical properties of a switchable Penrose quasiCrystal configuration in holographic polymer dispersed Liquid Crystal (H-PDLC) materials using a 5-beam hololithography exposure technique. The Penrose quasiCrystal structure is confirmed through diffraction patterns and scanning electron microscopy (SEM); both show the expected tenfold symmetry. We also present electro-optic switching parameters of this quasiCrystal structure and determine its index modulation to be 3×10−3 using coupled wave theory.
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tunable face centered cubic photonic Crystal formed in holographic polymer dispersed Liquid Crystals
Optics Letters, 2003Co-Authors: Michael J Escuti, Gregory P. CrawfordAbstract:We report on the fabrication and electro-optic measurements of face-centered-cubic (fcc) lattices in holographic polymer dispersed Liquid-Crystal materials. Four linearly polarized coherent plane waves were interfered to generate a fcc optical lattice that was subsequently and indefinitely recorded as an arrayed pattern of nanometer-sized Liquid-Crystal droplets ∼50 nm at lattice nodes within a polymer matrix. Observed transmission spectra and Kossel diffraction curves are consistent with fcc Crystal structure. A completely reversible 2% wavelength shift of the ±1 1 1 stop band was observed on application of an electric field.
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effect of monomer functionality on the morphology and performance of the holographic transmission gratings recorded on polymer dispersed Liquid Crystals
Macromolecules, 2003Co-Authors: Mousumi De Sarkar, Nicole L Gill, Gregory P. CrawfordAbstract:Transmission gratings were formed holographically in polymer dispersed Liquid Crystal (HPDLC) composite materials using commercially available UV-curable acrylate monomers and the nematic Liquid Crystal TL203. Monomer mixtures with average functionality ranging from 1.3 to 3.5 were used to prepare HPDLC transmission gratings. The phase-separated morphology and surface topology of the transmission gratings as observed through scanning electron microscopy and atomic force microscopy varied profoundly with the different monomer mixtures characterized by their average functionalities. The switching properties of the HPDLC gratings were correlated with the morphological changes.
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variable wavelength switchable bragg gratings formed in polymer dispersed Liquid Crystals
Applied Physics Letters, 2001Co-Authors: Chris C Bowley, Gregory P. Crawford, Pavel A Kossyrev, Sadeg M FarisAbstract:We report a holographic Polymer-Dispersed Liquid Crystal cell whose reflection peak can be tuned as a function of applied voltage. Electro-optic results are presented which are in excellent agreement with our model based on coupled wave theory.
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expanded viewing angle reflection from diffuse holographic polymer dispersed Liquid Crystal films
Applied Physics Letters, 2000Co-Authors: Michael J Escuti, Gregory P. Crawford, Pavel A Kossyrev, Thomas G Fiske, J Colegrove, Louis D SilversteinAbstract:A switchable diffuse reflective film with high color purity is demonstrated using holographic-polymer dispersed Liquid Crystals (HPDLC). By recording a diffuse hologram directly into the LC/polymer film, the diffuse mode HPDLC exhibit viewing angles an order of magnitude larger than the conventional mode. A simple phenomenological model based on coupled-wave theory is developed to describe our observations.
Jinyeong Park - One of the best experts on this subject based on the ideXlab platform.
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highly stretchable polymer dispersed Liquid Crystal based smart windows with transparent and stretchable hybrid electrodes
RSC Advances, 2018Co-Authors: Jinyeong ParkAbstract:We report on highly stretchable polymer dispersed Liquid Crystal (PDLC)-based smart windows using Ag nanowires (NWs) and conductive PEDOT:PSS hybrid electrodes. By bar coating a Ag NW and PEDOT:PSS mixed ink on a transparent and stretchable polyurethane (PU) substrate, we fabricated highly transparent and stretchable hybrid electrodes with a sheet resistance of 40 ohm per square, an optical transmittance of 82%, and a stretchability of 30% to replace conventional brittle ITO electrode. Bending and stretching tests demonstrated that the mechanical properties of the Ag NW and PEDOT:PSS hybrid electrode were better than those of the ITO/PU sample. The Ag NW/PEDOT:PSS hybrid film was employed as a transparent and stretchable electrode (TSE) in PDLC-based stretchable smart windows, an application that is impossible for brittle ITO-based smart windows. The stretchable PDLC-based smart windows exhibited an on-state transmittance of 56% at an applied voltage of 80 V and an off-state transmittance of 2% at 0 voltage. Unlike an ITO-based PDLC smart window, which is easily broken by stretching, the Ag NW/PEDOT:PSS hybrid electrode-based PDLC smart window was stretched up to 30%. Successful operation of the stretchable PDLC-based smart window indicates that Ag NW/PEDOT:PSS hybrid films are promising TSEs for cost-effective, large area, and stretchable smart windows.
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Liquid Crystal based flexible smart windows on roll to roll slot die coated ag nanowire network films
Journal of Alloys and Compounds, 2018Co-Authors: Dongju Kim, Jinyeong Park, Do Yun Hwang, Hanki KimAbstract:Abstract We developed polymer dispersed Liquid Crystal (PDLC)-based large-area flexible smart windows using continuous roll-to-roll (RTR) slot die–coated Ag nanowire (NW) percolating network electrodes. By simply printing Ag NW ink on flexible poly(ethylene terephthalate) (PET) substrates with 400 mm width, we fabricated cost-effective, transparent, and flexible Ag NW electrodes with a low sheet resistance of 50 Ohm/square and high transmittance of 88% for high-performance and large-area flexible PDLCs. Although the Ag NW electrode exhibited similar electrical and optical properties to typical indium tin oxide (ITO) electrodes, the Ag NW electrode had superior flexibility to the brittle ITO, which is important for flexible PDLCs. The PDLC window fabricated with the Ag NW electrode exhibited good transparency switching performance and outstanding flexibility. By producing a PDLC window with a width of 400 mm and length of 2 m, we demonstrated the feasibility of large-area flexible PLDCs based on continuous RTR-coated Ag NW electrodes for smart windows.
Li Xuan - One of the best experts on this subject based on the ideXlab platform.
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organic solid state tri wavelength lasing from holographic polymer dispersed Liquid Crystal and a distributed feedback laser with a doped laser dye and a semiconducting polymer film
Materials, 2017Co-Authors: M Liu, Yonggang Liu, Zenghui Peng, Shaoxin Wang, Qidong Wang, Zhaoliang Cao, Li XuanAbstract:Organic solid-state tri-wavelength lasing was demonstrated from dye-doped holographic Polymer-Dispersed Liquid Crystal (HPDLC) distributed feedback (DFB) laser with semiconducting polymer poly[-methoxy-5-(2′-ethyl-hexyloxy)-1,4-phenylene-vinylene] (MEH-PPV) and laser dye [4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran] (DCM) by a one-step holography technique, which centered at 605.5 nm, 611.9 nm, and 671.1 nm. The temperature-dependence tuning range for the tri-wavelength dye-doped HPDLC DFB laser was as high as 8 nm. The lasing emission from the 9th order HPDLC DFB laser with MEH-PPV as active medium was also investigated, which showed excellent s-polarization characterization. The diffraction order is 9th and 8th for the dual-wavelength lasing with DCM as the active medium. The results of this work provide a method for constructing the compact and cost-effective all solid-state smart laser systems, which may find application in scientific and applied research where multi-wavelength radiation is required.
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effects of monomer functionality on performances of scaffolding morphologic transmission gratings recorded in polymer dispersed Liquid Crystals
Journal of Physics D, 2015Co-Authors: Wenbin Huang, Donglin Pu, Su Shen, Li Xuan, Linsen ChenAbstract:The effects of monomer functionality on performances of holographic polymer dispersed Liquid Crystal (HPDLC) transmission gratings are systematically investigated. Acrylate monomers with an average functionality ranging from 2.0 to 5.0 are used to prepare these samples. We find scaffolding morphologic transmission gratings (characterized by a high phase separation degree, a well alignment of LCs and low scattering loss) can be obtained irrespective of the monomer functionality, although the exact optimal curing intensity varies. The temporal evolution of the grating formation is studied and the onset time of the LC phase separation decreases significantly with the increase in average monomer functionality. It is also shown that the gratings prepared from low average functionality monomers require a comparatively low switch-off electric field (~8 V μm−1) whilst suffering from mechanical fragility and long-term instability. Our results not only provide a complete understanding of scaffolding morphologic gratings in terms of the material composition effect, but also provide insight into the formation mechanisms of non-droplet morphologic HPDLC gratings.
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Enhancement of pump efficiency for an organic distributed feedback laser based on a holographic polymer dispersed Liquid Crystal as an external light feedback layer
Journal of Materials Chemistry C, 2015Co-Authors: Lijuan Liu, Minghuan Liu, Lifa Hu, Guiyang Zhang, Yonggang Liu, Li Xuan, Ji MaAbstract:We report a low threshold, high energy conversion organic distributed feedback (DFB) laser based on a holographic polymer dispersed Liquid Crystal (HPDLC) grating as an external light feedback layer, specifically, by adopting an acrylate-based monomer with low functionality and a rubbed polyimide (PI) alignment layer. In such configuration, the phase separated LCs were aligned along the preferred direction, which gave an increased refractive index difference between the LC and the polymer, so it can provide better light feedback in the HPDLC layer. The pump efficiency for the laser, such as lasing output threshold and conversion efficiency, can be enhanced. The light loss, diffraction efficiency and driving voltage were also investigated for the HPDLC structures to identify the effects of the rubbing layer and monomer functionality.
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organic dual wavelength distributed feedback laser empowered by dye doped holography
Journal of Materials Chemistry, 2012Co-Authors: Zhihui Diao, Wenbin Huang, Li Xuan, Shupeng Deng, Yonggang LiuAbstract:An organic dual-wavelength distributed feedback (DFB) laser empowered by a dye-doped holographic polymer dispersed Liquid Crystal (HPDLC) grating is reported for the first time. The dual-wavelength laser operates at 586.6 nm and 670.2 nm simultaneously in one laser beam via the seventh and eighth Bragg orders of a one dimensional (1D) HPDLC grating with a special period. We theoretically and experimentally demonstrate the mechanism of our dual-wavelength DFB laser and investigate the threshold and spectral properties of the output laser. Our organic dual-wavelength DFB laser shows the advantages of simple configuration, one-step fabrication, cost-effectiveness and the potential application to be integrated in all optical networks.
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theory and characteristics of holographic polymer dispersed Liquid Crystal transmission grating with scaffolding morphology
Applied Optics, 2012Co-Authors: Wenbin Huang, Yonggang Liu, Zhihui Diao, Chengliang Yang, Lishuang Yao, Li XuanAbstract:We have performed a detailed characterization of the optical properties of a holographic polymer dispersed Liquid Crystal (LC) transmission grating with polymer scaffolding morphology, which was fabricated with conventional high-functionality acrylate monomer under low curing intensity. Temporal evolution of the grating formation was investigated, and the amount of phase-separated LC was determined by birefringence investigation. A grating model combined with anisotropic coupled-wave theory yielded good agreement with experimental data without any fitting parameter. The results in this study demonstrate the non droplet scaffolding morphology grating is characterized by a high degree of phase separation (70%), high anisotropy, low scattering loss (<6%), and high diffraction efficiency (95%).
Henning Sirringhaus - One of the best experts on this subject based on the ideXlab platform.
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inkjet printing of polymer thin film transistor circuits
Mrs Bulletin, 2003Co-Authors: S E Burns, Paul A Cain, J Mills, Jizheng Wang, Henning SirringhausAbstract:We present a process for manufacturing printable thin-film transistors (TFTs) that is based on solution processing and direct inkjet printing of polymer semiconductors, dielectrics, and conductors, as well as inorganic nanoparticle conductors. We show that the high device yield, uniformity, and resolution required for thin-film electronic applications can be achieved by using a substrate that contains a surface energy pattern to control the flow and spreading of inkjet droplets. This technique overcomes many of the limitations of current inkjet printing technology related to its limited droplet placement accuracy. We demonstrate the potential of this printing-based TFT manufacturing process with the fabrication of 50 dpi active-matrix, polymer dispersed Liquid-Crystal and Gyricon Smartpaper electronic paper displays.