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Sheng-yang Wang - One of the best experts on this subject based on the ideXlab platform.
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New abietane-type diterpenoids from the bark of Cryptomeria japonica
Natural Product Communications, 2019Co-Authors: Chi I. Chang, Ming-jen Cheng, Cheng-chi Chen, Sheng-yang Wang, Jih-jung Cheng, Chin Hsu, Wei-yi Cheng, Ching-kuo Lee, Yueh-hsiung KuoAbstract:Two new abietane-type diterpenoids, 15-hydroxy-12-O-methylsugiol (1) and 2a-hydroxy-12-O-methylsugiol (2) were isolated from the methanol extract of the bark of Cryptomeria japonica. Their structur...
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Two new sesquarterpenoids from the bark of Cryptomeria japonica
Phytochemistry Letters, 2017Co-Authors: Chi I. Chang, Horng-huey Ko, Jih-jung Chen, Hsun-shuo Chang, Ming Der Wu, Ming-jen Cheng, Sheng-yang Wang, Cheng-chi ChenAbstract:Abstract Two new sesquarterpenoids, i.e. ferrugicadinol A (1) and ferrugicryptomeridiol (3), and one known sesquarterpenoid, ferrugicadinol (2) were isolated from the bark of Cryptomeria japonica D. Don. Their structures were identified by extensive spectral analysis and comparison with the data of known analogues.
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Two New Abietane-type Diterpenes from the Bark of Cryptomeria japonica:
Natural Product Communications, 2017Co-Authors: Chi I. Chang, Jih-jung Chen, Hsun-shuo Chang, Cheng-chi Chen, Sheng-yang Wang, Chienchih Chen, Cheyi Chao, Yueh-hsiung KuoAbstract:Phytochemical investigation of the methanol extract of the bark of Cryptomeria japonica has led to the isolation of two new abietane-type diterpenoids, 7a-(2’-butoxyethoxy)deoxocryptojaponol (1) an...
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Three new abietane-type diterpenes from the bark of Cryptomeria japonica
Phytochemistry Letters, 2017Co-Authors: Chi I. Chang, Jih-jung Chen, Hsun-shuo Chang, Cheng-chi Chen, Sheng-yang Wang, Chienchih Chen, Louis Kuoping Chao, Yueh-hsiung KuoAbstract:Abstract Three new abietane-type diterpenoids, 7α-butoxyabieta-8,12-diene-11,14-dione ( 1 ), 6α,7α-dihydroxyabieta-8,12-dien-11,14-dione ( 2 ), and 6α,7β-dihydroxyabieta- 8,12-diene-11,14-dione ( 3 ) were isolated from the bark of Cryptomeria japonica D. Don. Their structures were established by means of 1D and 2D NMR, IR, UV, and HR-EI-MS spectra and comparison with the data of known analogues.
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three new abietane type diterpenes from the bark of Cryptomeria japonica
Helvetica Chimica Acta, 2016Co-Authors: Chi I. Chang, Horng-huey Ko, Jih-jung Chen, Sheng-yang Wang, Chienchih Chen, Cheyi Chao, Louis Kuoping Chao, Cheng-chi ChenAbstract:Three new abietane-type diterpenoids, 7β-acetoxy-12-methoxyabieta-8,11,13-triene-6α,11-diol (1), 7α-acetoxy-12-methoxyabieta-8,11,13-triene-6α,11-diol (2), and 6α-acetoxy-12-methoxyabieta-8,11,13-triene-7α,11-diol (3), as well as two known abietane-type diterpenoids, 12-methoxyabieta-8,11,13-triene-6α,7β,11-triol (4) and 6α-acetoxy-12-methoxyabieta-8,11,13-triene-7β,11-diol (5), were isolated from the MeOH extract of the bark of Cryptomeria japonica. Their structures were determined by analysis of spectroscopic data and comparison of NMR data with those of related metabolites.
Cheng-chi Chen - One of the best experts on this subject based on the ideXlab platform.
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New abietane-type diterpenoids from the bark of Cryptomeria japonica
Natural Product Communications, 2019Co-Authors: Chi I. Chang, Ming-jen Cheng, Cheng-chi Chen, Sheng-yang Wang, Jih-jung Cheng, Chin Hsu, Wei-yi Cheng, Ching-kuo Lee, Yueh-hsiung KuoAbstract:Two new abietane-type diterpenoids, 15-hydroxy-12-O-methylsugiol (1) and 2a-hydroxy-12-O-methylsugiol (2) were isolated from the methanol extract of the bark of Cryptomeria japonica. Their structur...
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Two new sesquarterpenoids from the bark of Cryptomeria japonica
Phytochemistry Letters, 2017Co-Authors: Chi I. Chang, Horng-huey Ko, Jih-jung Chen, Hsun-shuo Chang, Ming Der Wu, Ming-jen Cheng, Sheng-yang Wang, Cheng-chi ChenAbstract:Abstract Two new sesquarterpenoids, i.e. ferrugicadinol A (1) and ferrugicryptomeridiol (3), and one known sesquarterpenoid, ferrugicadinol (2) were isolated from the bark of Cryptomeria japonica D. Don. Their structures were identified by extensive spectral analysis and comparison with the data of known analogues.
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Two New Abietane-type Diterpenes from the Bark of Cryptomeria japonica:
Natural Product Communications, 2017Co-Authors: Chi I. Chang, Jih-jung Chen, Hsun-shuo Chang, Cheng-chi Chen, Sheng-yang Wang, Chienchih Chen, Cheyi Chao, Yueh-hsiung KuoAbstract:Phytochemical investigation of the methanol extract of the bark of Cryptomeria japonica has led to the isolation of two new abietane-type diterpenoids, 7a-(2’-butoxyethoxy)deoxocryptojaponol (1) an...
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Three new abietane-type diterpenes from the bark of Cryptomeria japonica
Phytochemistry Letters, 2017Co-Authors: Chi I. Chang, Jih-jung Chen, Hsun-shuo Chang, Cheng-chi Chen, Sheng-yang Wang, Chienchih Chen, Louis Kuoping Chao, Yueh-hsiung KuoAbstract:Abstract Three new abietane-type diterpenoids, 7α-butoxyabieta-8,12-diene-11,14-dione ( 1 ), 6α,7α-dihydroxyabieta-8,12-dien-11,14-dione ( 2 ), and 6α,7β-dihydroxyabieta- 8,12-diene-11,14-dione ( 3 ) were isolated from the bark of Cryptomeria japonica D. Don. Their structures were established by means of 1D and 2D NMR, IR, UV, and HR-EI-MS spectra and comparison with the data of known analogues.
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three new abietane type diterpenes from the bark of Cryptomeria japonica
Helvetica Chimica Acta, 2016Co-Authors: Chi I. Chang, Horng-huey Ko, Jih-jung Chen, Sheng-yang Wang, Chienchih Chen, Cheyi Chao, Louis Kuoping Chao, Cheng-chi ChenAbstract:Three new abietane-type diterpenoids, 7β-acetoxy-12-methoxyabieta-8,11,13-triene-6α,11-diol (1), 7α-acetoxy-12-methoxyabieta-8,11,13-triene-6α,11-diol (2), and 6α-acetoxy-12-methoxyabieta-8,11,13-triene-7α,11-diol (3), as well as two known abietane-type diterpenoids, 12-methoxyabieta-8,11,13-triene-6α,7β,11-triol (4) and 6α-acetoxy-12-methoxyabieta-8,11,13-triene-7β,11-diol (5), were isolated from the MeOH extract of the bark of Cryptomeria japonica. Their structures were determined by analysis of spectroscopic data and comparison of NMR data with those of related metabolites.
Yueh-hsiung Kuo - One of the best experts on this subject based on the ideXlab platform.
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New abietane-type diterpenoids from the bark of Cryptomeria japonica
Natural Product Communications, 2019Co-Authors: Chi I. Chang, Ming-jen Cheng, Cheng-chi Chen, Sheng-yang Wang, Jih-jung Cheng, Chin Hsu, Wei-yi Cheng, Ching-kuo Lee, Yueh-hsiung KuoAbstract:Two new abietane-type diterpenoids, 15-hydroxy-12-O-methylsugiol (1) and 2a-hydroxy-12-O-methylsugiol (2) were isolated from the methanol extract of the bark of Cryptomeria japonica. Their structur...
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Two New Abietane-type Diterpenes from the Bark of Cryptomeria japonica:
Natural Product Communications, 2017Co-Authors: Chi I. Chang, Jih-jung Chen, Hsun-shuo Chang, Cheng-chi Chen, Sheng-yang Wang, Chienchih Chen, Cheyi Chao, Yueh-hsiung KuoAbstract:Phytochemical investigation of the methanol extract of the bark of Cryptomeria japonica has led to the isolation of two new abietane-type diterpenoids, 7a-(2’-butoxyethoxy)deoxocryptojaponol (1) an...
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Three new abietane-type diterpenes from the bark of Cryptomeria japonica
Phytochemistry Letters, 2017Co-Authors: Chi I. Chang, Jih-jung Chen, Hsun-shuo Chang, Cheng-chi Chen, Sheng-yang Wang, Chienchih Chen, Louis Kuoping Chao, Yueh-hsiung KuoAbstract:Abstract Three new abietane-type diterpenoids, 7α-butoxyabieta-8,12-diene-11,14-dione ( 1 ), 6α,7α-dihydroxyabieta-8,12-dien-11,14-dione ( 2 ), and 6α,7β-dihydroxyabieta- 8,12-diene-11,14-dione ( 3 ) were isolated from the bark of Cryptomeria japonica D. Don. Their structures were established by means of 1D and 2D NMR, IR, UV, and HR-EI-MS spectra and comparison with the data of known analogues.
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cytotoxic c 35 terpenoid cryptotrione from the bark of Cryptomeria japonica
Organic Letters, 2010Co-Authors: Cheng-chi Chen, Ningsun Yang, Jang Yang Chang, Sheng-yang Wang, Chingchuan Kuo, Yueh-hsiung KuoAbstract:A novel C35-terpene, designated as cryptotrione (1), with an unprecedented skeleton possessing an abietane diterpene with a unique bicyclic sesquiterpene, is identified from the bark of Cryptomeria japonica. The carbon skeleton of 1 represents a new structural entity, and this is an intriguing addition to the structurally diverse diterpene-sesquiterpene class. A unique biosynthetic pathway is proposed to support the production of this phytocompound. Notably, 1 exhibits anticancer activity with an IC50 value of 6.44 ± 2.23 μM.
Tadashi Ishii - One of the best experts on this subject based on the ideXlab platform.
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Xyloglucan from xylem-differentiating zones of Cryptomeria japonica
Phytochemistry, 1998Co-Authors: Koichi Kakegawa, Yusuke Edashige, Tadashi IshiiAbstract:Abstract Xyloglucan was isolated from xylem-differentiating zones of Cryptomeria japonica . Endo-1,4-β-glucanase digestion of the xyloglucan gave a series of oligosaccharides. These oligosaccharides were purified by gel permeation chromatography and normal-phase HPLC. Glycosyl-residue composition and glycosyl-linkage composition analyses, 1 H NMR spectroscopy and FAB-mass spectrometry of the oligosaccharides showed that the xyloglucan was composed of five kinds of oligosaccharide. These oligosaccharides are commonly found in xyloglucan from dicot plants and are characterized as XXXG, XXLG, XXFG, XLLG and XLFG. These results suggest that xyloglucan from gymnosperms has similar structure to that of dicots.
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Rhamnogalacturonan I from xylem differentiating zones of Cryptomeria japonica
Carbohydrate Research, 1997Co-Authors: Yusuke Edashige, Tadashi IshiiAbstract:Abstract Rhamnogalacturonan I (RG-I) was isolated from the pectin of the cell wall of xylem differentiating zones of sugi (Cryptomeria japonica D. Don, gymnosperm) by digesting with endo-α-1,4-polygalacturonase followed by gel-permeation chromatography. Structure of RG-1 was characterized by glycosyl composition and glycosyl linkage analyses, partial acid hydrolysis, and lithium (Li)-treatment in ethylenediamine. The oligosaccharides produced by partial acid hydrolysis showed the backbone of RG-I to be a disaccharide repeating unit of → 4)-α- d -Gal p A-(1 → 2)-α- l -Rha p- (1 → . Arabinan and oligogalactosyl side chains were attached at O-4 of rhamnosyl residues of the backbone. Glycosyl composition and glycosyl linkage analyses suggested that the structures and/or the distribution of the arabinan sidechains of sugi RG-I were different from those of sycamore (angiosperm) RG-I. The backbone of sugi (Cryptomeria japonica D. Don, gymnosperm) rhamnogalacturonan I (RG-I) comprises a disaccharide repeating unit → 4)-α- d -Gal p A -(1 → 2)-α- l -Rha p-(1 → . Arabinan and oligogalactosyl sidechainds are attached at O-4 of rhamnosyl residues of the backbones.
Kazuhiko Fukushima - One of the best experts on this subject based on the ideXlab platform.
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Decontamination of Cs from Japanese cedar (Cryptomeria japonica) via kraft cooking
Journal of Wood Science, 2017Co-Authors: Wei Wang, Rie Tomioka, Dan Aoki, Kazuya Iizuka, Kazuhiko Fukushima, Yasuyuki Matsushita, Chisato TakenakaAbstract:To investigate the possibility of decontaminating ^137Cs-contaminated Cryptomeria japonica wood, kraft pulping was conducted and the Cs behavior in the reaction process was examined. ^133Cs-treated or ^137Cs-contaminated bark, sapwood, and heartwood chips of Cryptomeria japonica were digested using an aqueous solution of NaOH and Na_2S. The pulp was washed with ultrapure water and filtered, after which the filtrate (black liquor) was collected. The black liquor was acidified to separate the supernatant and precipitation. The Cs (^133Cs and ^137Cs) concentrations in the chip and reaction products were measured. As for wood samples, the majority of Cs was present in black liquor, while only a minor amount of Cs was retained in the pulp (
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Translocation of 133Cs administered to Cryptomeria japonica wood
Science of The Total Environment, 2017Co-Authors: Dan Aoki, Rie Tomioka, Yasuyuki Matsushita, Ryutaro Asai, Hiroyuki Asakura, Masao Tabuchi, Kazuhiko FukushimaAbstract:To reveal the in planta behaviour of caesium (Cs), the stable isotope 133Cs was administered into 3-year-old Cryptomeria japonica seedlings by the application of 133CsCl aqueous solution to the bark surface. The administered 133Cs was quantified by ICP-MS measurements, which showed transportation of 133Cs in an ascending direction in the stem. Distribution of 133Cs was visualized using freeze-fixed C. japonica woody stem samples and cryo-time-of-flight secondary ion mass spectrometry/scanning electron microscopy (cryo-TOF-SIMS/SEM) analysis. Cryo-TOF-SIMS/SEM visualization suggested that 133Cs was rapidly transported radially by ray parenchyma cells followed by axial transportation by pith and axial parenchyma cells. Adsorption experiments using powdered C. japonica wood samples and X-ray absorption fine structure (XAFS) analysis suggested that 133Cs was in the hydrated state following its deposition into tracheid cell walls.
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Clonal variation in heartwood norlignans of Cryptomeria japonica: evidence for independent control of agatharesinol and sequirin C biosynthesis
Annals of Forest Science, 2011Co-Authors: Nobumasa Bito, Kazuhiko Fukushima, Yasuyuki Matsushita, Ryogo Nakada, Eitaro Fukatsu, Takanori ImaiAbstract:• Introduction In Cryptomeria japonica, heartwood properties are considered to be affected by specific extractives. It remains unclear whether traits of specific heartwood compounds are under genetic control.